化学与材料学院——张霄研究员
发布时间:2020-09-21 浏览次数: 296


张霄,研究员,博士生导师

邮箱zhangxiao@fjnu.edu.cn

通讯地址:福建省福州市仓山区上三路金沙澳门登录网站化学楼东203室   邮编350007

课题组常年招收硕士研究生以及博士研究生,热忱欢迎勤奋踏实、积极上进的同学加盟!

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(欢迎感兴趣的同学联系大家大家将第一时间予以回复

 

个人简历

2020.04 - 至今     金沙澳门登录网站化学与材料学院,研究员

2018.06 - 2020.03   中国科学院上海有机化学研究所金属有机国家重点实验室,副研究员

2017.09 - 2018.05   中国科学院上海有机化学研究所金属有机国家重点实验室,助理研究员

2015.09 - 2017.08   德国马尔堡大学,博士后洪堡学者(合作导师Eric Meggers 教授)

2010.09 - 2015.07   中国科学院上海有机化学研究所金属有机国家重点实验室,博士(导师游书力研究员)

2006.09 - 2010.07   安徽师范大学化学与材料科学学院,学士

 

研究兴趣:

光化学合成,不对称催化

 

荣誉与获奖情况:

2020 福建省闽江学者特聘教授

2019 中国科学院青年创新促进会会员

2018 上海市青年科技英才扬帆计划

2015-2017 德国亚历山大??洪堡奖学金

 

代表性论文/著作:

1. Cheng, Y.-Z.; Huang, X.-L.; Zhuang, W.-H.; Zhao, Q.-R.; Zhang, X.*; Mei, T.-S.*; You, S.-L.* Intermolecular Dearomatization of Naphthalene Derivatives by PhotoredoxCatalyzed 1,2Hydroalkylation. Angew. Chem. Int. Ed. 2020, 59, https://doi.org/10.1002/anie.202008358. (SCI 一区, IF 12.959)

2. Zhu, M.; Huang, X.-L.; Xu, H.; Zhang, X.*; Zheng, C.*; You, S.-L.* Visible-Light-Mediated Synthesis of Cyclobutene-Fused Indolizidines and Related Structural Analogs. CCS Chem. 2020, 2, 652-664. (SCI 一区, IF --)

3. Cheng, Y.-Z.; Zhao, Q.-R.; Zhang, X.*; You, S.-L.* Asymmetric Dearomatization of Indole Derivatives with N-Hydroxycarbamates Enabled by Photoredox Catalysis. Angew. Chem. Int. Ed. 2019, 58, 18069-18074. (SCI 一区, IF 12.959)

4. Zhu, M.; Zheng, C.*; Zhang, X.*; You, S.-L.* Synthesis of Cyclobutane-Fused Angular Tetracyclic Spiroindolines via Visible-Light-Promoted Intramolecular Dearomatization of Indole Derivatives. J. Am. Chem. Soc. 2019, 141, 2636-2644. (SCI 一区, IF 14.612)

5. Xu-Xu, Q.-F.; Liu, Q.-Q.; Zhang, X.*; You, S.-L.* Copper-Catalyzed Ring Opening of Benzofurans and Enantioselective Hydroamination Cascade. Angew. Chem. Int. Ed. 2018, 57, 15204-15208. (SCI 一区, IF 12.959)

6. Tu, H.-F.#; Zhang, X.#; Zheng, C.; Zhu, M.; You, S.-L.* Enantioselective dearomative prenylation of indole derivatives. Nat. Catal. 2018, 1, 601-608. (Tu, H.-F. and Zhang, X. contribute equally) (SCI 一区, IF 30.471) 

7. Ma, J.#; Zhang, X. #; Huang, X.; Luo, S.; Meggers, E.* Preparation of Chiral-at-Metal Catalysts and their Use in Asymmetric Photoredox Chemistry. Nat. Protoc. 2018, 13, 605-632. (Ma, J. and Zhang, X. contribute equally) (SCI 一区, IF 10.419)

8. Xu-Xu, Q.-F.; Zhang, X.*; You, S.-L.* Enantioselective Synthesis of 4?Aminotetrahydroquinolines via 1,2-Reductive Dearomatization of Quinolines and Copper(I) Hydride Catalyzed Asymmetric Hydroamination. Org. Lett. 2019, 21, 5357-5362. (SCI 一区, IF 6.091) 

9. Bao, C.-C.; Zheng, D.-S.; Zhang, X.*; You, S.-L.* Iridium/N-Heterocyclic Carbene Complex-Catalyzed Intermolecular Allylic Alkylation Reaction. Organometallics 2018, 37, 4763-4772. (Bao, C.-C. and Zheng, D.-S. contribute equally) (SCI 二区, IF 3.804)

10. Zhu, M.; Zhou, K.; Zhang, X.*; You, S.-L.* Visible-Light-Promoted Intramolecular Trifluoromethylative Dearomatization of Indole Derivatives via Intermolecular Charge Transfer. Org. Lett. 2018, 20, 4379-4383. (SCI 一区, IF 6.091)

11. Cheng, Y.-Z.; Zhou, K.; Zhu, M.; Li, L.-A.-C.; Zhang, X.*; You, S.-L.* Visible-Light Promoted Intermolecular Oxidative Dearomatization of β-Naphthols with N-Hydroxycarbamates. Chem. Eur. J. 2018, 24, 12519-12523. (SCI 二区, IF 4.857)

12. Cheng, Y.-Z.; Zhang, X.*; You, S.-L.* Visible light mediated photocatalysis as a new tool for catalytic asymmetric dearomatization (CADA) reactions. Sci. Bull. 2018, 63, 809-811. (SCI 一区, IF 9.511)

13. Zhang, X.; You, S.-L.* Removing the Mask in Catalytic Asymmetric Diamination of Alkenes. Chem. 2017, 2, 917-919. (SCI 一区, IF 19.735)

14. Zhang, X.; Yang, Z.-P.; Huang, L.; You, S.-L.* Highly Regio- and Enantioselective Synthesis of N-Substituted 2-pyridones via Ir-Catalyzed Intermolecular Asymmetric Allylic Amination. Angew. Chem. Int. Ed. 2015, 54, 1873-1876. (SCI 一区, IF 12.959)

15. Zhang, X.; Liu, W.-B.; Tu, H.-F.; You, S.-L.* Ligand-Enabled Ir-Catalyzed Intermolecular Diastereoselective and Enantioselective Allylic Alkylation of 3-Substituted Indoles. Chem. Sci. 2015, 6, 4525-4529. (SCI 一区, IF 9.346)

16. Zhang, X.; Han, L.; You, S.-L.* Ir-Catalyzed Intermolecular Asymmetric Allylic Dearomatization Reaction of Indoles. Chem. Sci. 2014, 5, 1059-1063. (SCI 一区, IF 9.346)

17. Zhang, X.; Yang, Z.-P.; Liu, C.; You, S.-L.* Ru-Catalyzed Intermolecular Dearomatization Reaction of Indoles with Allylic Alcohols. Chem. Sci. 2013, 4, 3239-3243. (SCI 一区, IF 9.346)

18. Zhang, X.; You, S.-L.* Asymmetric Allylic Substitutions Catalyzed by Iridium Complexes Derived from C(sp2)–H Activation of Chiral Ligands. Aldrichimica Acta. 2020, 53, 11-18. (SCI 一区, IF 7.80)

19. Zhang, X., You, S.-L.; Science of Synthesis: Metal-Catalyzed Cyclization Reactions 1. (Volume Editors: Ma, S.; Gao, S.) Chapter 3. Metal-Catalyzed Intramolecular Allylic Substitution Reactions. 2016, 95-150.

20. Zhang, X.; You, S.-L.* THQphos in Ir-Catalyzed Asymmetric Allylic Substitution Reactions. Chimia 2018, 72, 589-594. (Invited paper for Homogeneous Catalysis – New Transformations and Mechanistic Insights Special Issue)

21. Zhang, X.; Qin, J.; Huang, X.; Meggers, E.* One-Pot Sequential Photoredox Chemistry and Asymmetric Transfer Hydrogenation with a Single Catalyst. Eur. J. Org. Chem. 2018, 2018, 571-577. (SCI 三区, IF 2.889)

22. Zhang, X.; Qin, J.; Huang, X.; Meggers, E.* Sequential Asymmetric Hydrogenation and Photoredox Chemistry with a Single Catalyst. Org. Chem. Front. 2018, 5, 166-170. (SCI 二区, IF 5.155)

23. Zhang, X.; Liu, W.-B.; Cheng, Q.; You, S.-L.* Iridium-Catalyzed Asymmetric Allylic Amination Reaction with N-Aryl Phosphoramidite Ligands. Organometallics 2016, 35, 2467-2472. (SCI 二区, IF 3.804) 

24. Zhang, X.; Wu, Q.-F.; Liu, W.-B.; You, S.-L.* Ruthenium-Catalyzed Intramolecular Allylic Dearomatization Reaction of Indole Derivatives Org. Lett. 2013, 15, 3746-3749. (SCI 一区, IF 6.091)

25. Tang, S.-B.; Zhang, X.; Tu, H.-F.; You, S.-L.* Regio- and Enantioselective Rhodium-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with 1,3-Diketones. J. Am. Chem. Soc. 2018, 140, 7737-7742. (SCI 一区, IF 14.612)

26. Liu, W.-B.; Zhang, X.; Dai, L.-X.; You, S.-L.* Asymmetric N-Allylation of Indoles via Ir-Catalyzed Allylic Alkylation of Indolines and Oxidation Strategy. Angew. Chem. Int. Ed. 2012, 51, 5183-5187. (SCI 一区, IF 12.959)

27. Zhuo, C.-X.; Zhang, X.; You, S.-L.* Enantioselective Synthesis of Pyrrole-Fused Piperazine and Piperazinone Derivatives via Ir-Catalyzed Asymmetric Allylic Amination. ACS Catal. 2016, 6, 5307-5310. (SCI 一区, IF 12.35)

28. Xu-Xu, Q.-F.; Zhang, X.; You, S.-L.* Enantioselective Synthesis of 4-Allyl Tetrahydroquinolines via Copper(I) Hydride-Catalyzed Hydroallylation of 1,2-Dihydroquinolines. Org. Lett. 2020, 22, 1530. (SCI 一区, IF 6.091) 

29. Tang, S.-B.; Tu, H.-F.; Zhang, X.; You, S.-L.* Rhodium-Catalyzed Asymmetric Allylic Dearomatization of β-Naphthols: Enantioselective Control of Prochiral Nucleophiles. Org. Lett. 2019, 21, 6130-6134. (SCI 一区, IF 6.091)

30. Shao, W.; Wang, Y.; Yang, Z.-P.; Zhang, X.; You, S.-L.* Efficient Synthesis of N-Alkylated 4-Pyridones by Copper-Catalyzed Intermolecular Asymmetric Propargylic Amination. Chem. Asian. J. 2018, 13, 1103-1107. (SCI 二区, IF 4.056)

31. Luo, S.; Zhang, X.; Zheng, Y.; Harms, K.; Zhang, L.; Meggers, E.* Enantioselective Alkynylation of Aromatic Aldehydes Catalyzed by a Sterically Highly Demanding Chiral-at-Rhodium Lewis Acid. J. Org. Chem. 2017, 82, 8995-9005. (SCI 二区, IF 4.335)

32. Ye, K.-Y.; Zhang, X.; Dai, L.-X.; You, S.-L.* Ruthenium-Catalyzed Regioselective Allylic Trifluoromethylthiolation Reaction. J. Org. Chem. 2014, 79, 12106-12110. (SCI 二区, IF 4.335)

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